( L - R ) Jennifer Aniston, Angelina Jolie - file photos

Bangshowbiz

Angelina Jolie and Jennifer Aniston are set to battle it out on the cover of W magazine.

Jennifer - whose marriage to Brad Pitt ended shortly after he starred in Mr. and Mrs. Smith with Angelina - and the Tomb Raider actress both star on separate covers of the November edition of the glossy publication entitled The Art Issue.

A source said: "It's like a rematch between Angelina and Jennifer. Angelina might have won Brad but who will sell more magazine covers?!"

Brad and Angelina posed for a W magazine photoshoot as the perfect suburban couple playing with their children in June 2005, even though the actor was still officially married to Jennifer.

Brad and Jennifer finalised their divorce in October 2005.

After her break-up from Brad, Jennifer posed for numerous magazine covers bearing headlines such as 'I'll survive' and 'I'm OK'.

Brad and Angelina have three adopted children, Maddox, six, Pax, three and Zahara, two, and 16-month-old biological daughter Shiloh.